Solid fuel tablets and a fire steel both help you make heat when the mains and the gas are off, but they play different parts in the same process. Solid fuel tablets — hexamine blocks, FireDragon cubes or natural firelighters — are the fuel. Each tablet is a compact, stable block that lights easily and burns for several minutes with a steady flame, enough to boil a mug of water on a small folding stand or get a stubborn campfire going. They store for years, are unaffected by cold, and give you controllable heat without a gas canister.
A fire steel is the opposite: it makes no heat of its own. It is a rod of ferrocerium that throws a shower of very hot sparks when scraped with a striker, and it works soaking wet, in wind and at altitude where a lighter might fail. On its own a fire steel does nothing useful — you need something for those sparks to catch, whether that is tinder, a natural firelighter or, indeed, a solid fuel tablet. One is the thing that burns; the other is the reliable way to start it burning.